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Redox reaction-induced polymorphism in DNA crystals of the phosphorothioate analog of 2′-deoxyguanosine.
We have observed remarkable polymorphism in the crystal structures of a phosphorothioate analog of 2′-deoxyguanosine. Five different polymorphs of the same molecular entity have been determined by X-ray diffraction. These polymorphs have a range of melting points, and are redox active and crystallizable under various conditions. Crystals of the phosphorothioate are stable and are stable in solution and against degradation by oxidants. The structures differ in the arrangement of hydrogen bonds within the crystal lattice and in stacking interactions of the base and sugar. The data suggest that this compound may be potentially useful for developing new lead compounds for cancer chemotherapy.The Universe Of Opinions: Year 4
By Steve Orlowski || It’s hard to believe the last 5 years have flown by. For most of us, it seems just yesterday that the second-to-last episode of the 2017 season was being aired. Without
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